Sani san 1863 ka se, siliyɔmu-Fɛn minnu bɛ sɔrɔ mɔgɔw fɛ, olu bɛɛ tun ye siliyɔmu fɛnɲɛnamafagalan ye min tɛ fɛnɲɛnamaw ye, siliyɔmu nafama-Fɛn minnu bɛ wuli ka kɛ bi fɛnw ye i n’a fɔ seramiki, siman, ani gilasi. San 1863, Faransi furakɛlikɛlaw C. Feidedel ani JM Raft ye tetaraɛtili silane dilan ni etili zinki ni silimɔni tetarafluoride ka ɲɔgɔn sɔrɔli ye tuubu datugulen kɔnɔ. O tun ye organosilicon fɔlɔ ye tariku kɔnɔ. O fana kɛra Organosilicon chimie daminɛ ye.
Kabini o waati, furakɛlikɛlaw bɛ to ka organosilicon fɛnɲɛnamafagalan kuraw dilan. Among them, it is worth mentioning A. Lamenberg, which uses ethyl orthosilicate to replace silicon tetrachloride and react with alkyl zinc to obtain organosilicon compounds with mono -, II -, and III silicon functionals, and A.Polis, which synthesizes the first all-arylsilane, tetraphenylsilane, through the CAWurtz reaction. San 40 kɔnɔ fo ka se san 1903 ma, hali ni fɛɛrɛko ɲɛtaa si ma sɔrɔ tiɲɛ na silikoni yiriwali la, furakɛlikɛlaw ye baara caman kɛ tutigɛbagaya la o waati kɔnɔ. O la, nin dakun in bɛ Se ka Jate silikoni daminɛ waati ye.
Angletɛri furakɛlikɛla tɔgɔba Fskipping bɛ jate Organosilicon chimie sigibaga ye. K’a ta san 1898 la ka se san 1944 ma, a ye ɲinini caman kɛ ani ka don o baara in na ani ka sɛbɛn 51 bɔ minnu bɛ tali kɛ o ko la, o ye gafe 51 bɔ, minnu bɛ bɔ The Journal of the Chemical Society of the United Kingdom kɔnɔ.
San 1904, W ni Alemaɲi furakɛlikɛla Dithey y’a ye u yɛrɛma ko organosilicon compounds bɛ se ka dilan ni grignard reaction ye. O fɛɛrɛ in ɲɛnabɔra kosɛbɛ nɛgɛ-nɔgɔya fɛɛrɛ kɔrɔw kan k’a sababu kɛ a baara nɔgɔya ye, a sɔrɔcogo ka bon, a kɛcogo caman ani a lakanani ka bon kosɛbɛ. Nin fɛɛrɛ in bɛ se ka kɛ ka organosilicon suguya caman dilan ni silikoni baarakɛcogo wɛrɛw ye .
Kip-Ping ye kɔlɔn hakɛ caman sɔrɔ-Organosilicon fɛnɲɛnamafagalan ɲɛfɔlenw ni nin fɛɛrɛ in ye. O fɛɛrɛ in kɛra organosiliconw ka baara jusigilan ye don nataw la, wa a tora organosilicon ka sinti fɛɛrɛ nafama dɔ ye bi. RMGCL+SICL- RSICL:+RSICL+R:SIC1+ RSI +MGCL,(2.3)Kolorosilan minnu dilannen don ni Grignard Reagent fɛɛrɛ ye, olu bɛ se ka kɛ silanɔli ye. O waati kelen na, a y’a kɔlɔsi fana ko silanidiol ni siltriol bɛ se ka taa ɲɛ ka taa a fɛ ni polimɛriw ye. Nka, i n’a fɔ fɛnɲɛnamafagalan, a ma a janto o wale in na hali dɔɔnin ani a yɛrɛ ye o polimɛri fɛn ninnu kɔniya. O la sa, a ma u kalan. O siratigɛ la, dilthey ye baara kɔrɔ dɔ kɛ tiɲɛ na: a ye difenilisiladiol condensed walasa ka hexaphenylcyclotrisiloxane sɔrɔ. Nin ye polisiloxane fɛnɲɛnamafagalan fɔlɔ ye min fɔra tariku kɔnɔ. A ye tutigɛbaga ye silikoni liniyali la-oxane, wa a nali ye jɔyɔrɔba ta kosɛbɛ organosilicon polimɛriw yiriwali sabatili la.
K’a ta san 1904 la ka na se san 1937 ma, dɔnnikɛlaw ma dɔrɔn ka organosilikɔn nɔgɔman caman dilan, nka u ye polisilokisisakaridi cyclique ni lineaire fana dilan. Ka fara o kan, A.Stock ye silanhidride caman sɔrɔ ɲinini jɔnjɔnw na, wa a ye silikomɛ atomu atomu amimɛtiriw labɛnni daminɛ. San tan saba tɛmɛnenw kɛra organosilicon chimie ka bonya waati ye.
San 1930w kɔfɛ, furakɛlikɛlaw y’a daminɛ ka baara kɛcogo jigiyaw dɔn minnu bɛ sɔrɔ sanfɛ-Molecular Organosilicon faralenw kan. Ɲininikalan fɔlɔ minnu kɛra o baara la, olu ye JFHYDE of Corning Glass Company ye Ameriki, WJ Petnode ani EgroChow ka bɔ General Electric (GE) la Ameriki, ani ka Ka ka bɔ Soviyetiki jamana kɔrɔ Andrianov ani Bndolgov, R. Miller ka bɔ Alimanjamana na, a ɲɔgɔnnaw
Hyde, min bɛ Kipping ka jate la, ale de ye fɔlɔ ye ka organosilicon chimie ni polimɛri chimie fara ɲɔgɔn kan. A ka bilasirali kɔnɔ, Corning Inc. ye silikoni resinw, finiw, fɛnɲɛnamafagalanw ani poligaziloloksan fɛn caman wɛrɛw dilan minnu bɛ kɛ ka kuran insulating gilasi fini don. O waati kelen na, Ameriki ka dowkimikiw fana ye polyorganosiloxanes dilanni ɲinini daminɛ ani jiri pilotiw sigilen dimetil silikoni tulu ni metil fenili silikoni resin na san 1942. O waati la, organochlorosilane monomɛriw tun bɛ sɔrɔ kɛrɛnkɛrɛnnenya la grignard fɛɛrɛ fɛ, o la, monomɛriw sɔrɔli kɛra waatiba ye min bɛ se ka kɛ sababu ye ka ɲɛnamaya kɛcogo ɲɛ. San 1940, Rochow ye metilsilane ka "direct synthèse method" dabɔ ani ka patenti ɲini. Nin fɛɛrɛ in tɛ baara kɛ ni furajiw ye. O ye gazi-fasa solidi ye min kɔnɔ, kulorometan bɛ don silikon mugu la, nɛgɛ katalisita bɛ min kɔnɔ (Equation 2.4). Nin waati in na dɔrɔn, Alemaɲi furakɛlikɛla Muller fana ye o ɲɔgɔnna patenti ɲini, nka a fɔlɔ don kɛra kalo kɔnɔntɔn kɔfɛ ka tɛmɛ Rochow ta kan. O dɛmɛba in ye fɛnba dɔ lawuli silikoni dilanni na ani ka silikoni yiriwali yiriwa ka taa a fɛ.
San 1943, Dow Chemical Company ani Corning Inc. ye ɲɔgɔn sɔrɔ diɲɛ kɔnɔ-Silikoni baarakɛlaw ka tɔn tɔgɔla - Dow Corning Corporation, ani o san kelen na, izini dɔ jɔra Mdand, Michigan, Ameriki. Sosiyete ye DC#4 tasuma-fanga-minɛn dilan joona ani k’a kɛ ka ɲɛ ka ɲɛsin awiyɔnw ma minnu ka bon ni{6}}Altitude ye. Kɔfɛ, a ka baarakɛyɔrɔ ye silikoni resin suguya caman dilan, ka a datugu, ka tulu kɛ tulu la, ka tulu kɛ tulu la, ka defoamers ani fɛn wɛrɛw dilan. San 1947, General Electric Company fana ye Organosilicon Division dɔ sigi sen kan, min ye gazi organosilicon dilan ni fɛɛrɛ tilennen ye ani ka polisiloxane fɛnw dilan. General Electric Company ka fɛn dilanni fɛɛrɛ in tara silikoni iziniw fɛ minnu bɛ tugu o kɔ.
Sɛgɛsɛgɛli min kɛra silikoni polimɛriw kan Soviyetiki jamana kɔrɔ la, o tun ye ko ye min tun ka bon kosɛbɛ, kɛrɛnkɛrɛnnenya la Andrianov. Ka fara baara caman kɛli kan polisiloxane polimɛriw kan ani ka polimɛri organosilikɔli caman dilan ni nafa waleyali ye, a ye fɛn wɛrɛw fana don i n’a fɔ boron, aluminiyɔmu, titaniyɔmu, tin ani fosiporozɛni ka don polisiloksan jɔcogo la walasa ka fɛn caman sɛmɛntiya. Ale fana ye mɔgɔ fɔlɔ ye min ye silazane kɛ ji ma se ka don a la.
Diɲɛ kɛlɛba filanan bannen kɔfɛ, k’a sababu kɛ silikoni ka fɛn dilannenw ye ɲɛtaa sɔrɔ sɔrɔdasiya la, silikoni baara yiriwara teliya la kosɛbɛ ani a dilanni bɛɛ ye sira basigilen dɔ daminɛ. San 1950 waatiw la, silikoni fɛn dilanko tɔnw sigira senkan jamana caman na. Silikɔni polimɛri fɛn suguya caman, i n’a fɔ silikoni (o la, a ka bon-sumaya furakɛli lastikuw, so funteni min bɛ tiɲɛ, silikoni lastikuw transparent, tulu{4}} resistant fluorosilinikɔli, a ɲɔgɔnnaw), diffusion pompe tulu, laminating resin, silicone emulsion, silicone suffant, anti{6}stique ambrame, wdfl. kelen bɛ kɛ kelen ye.
San 1938 ni 1965 cɛ, hakilina ni waleyali siratigɛ la; Organosilicon chimie bɛ ka ɲɛtaa teliya monomɛriw ni polimɛriw bɛɛ la. Yan, hakilina jɔnjɔn minnu ka kan ka sinsin, olu ye : silisilɛriw ka waleyaw, jilafɛnw waleyali, ɲinini minnu bɛ kɛ ni fototalan ye, olu ye fɛnɲɛnamafagalanw ye minnu bɛ sɔrɔ fɛnɲɛnamafagalanw na, minnu bɛ ni karɔbɔni baarakɛta kuluw ye, farikoloɲɛnajɛ kɛcogoyaw ɲɛnabɔli, ani polimɛrizi fɛɛrɛw ɲɛnabɔli, ani silikoni tulu bɔli kɔfɛ, silikoni lastikuw, ani kupulingɛw, a ɲɔgɔnnaw, o tɛ kɛ sababu ye nin waati in na, nin waati in tun tɛ se ka kɛ ko nin waati in tun ye ko nin ye ko nin waati in tun ye ko nin waati in tun ye ko nin waati in tun ye ko nin waati in tun ye ko nin waati in tun ye ko nin waati in tun ye ko nin waati in tun ye ko nin waati in tun ye ko nin waati in tun bɛ kɛ ko nin waati in tun ye ko nin waati in tun ye ko nin waati in tun bɛ kɛ ko nin waati in tun ye ko nin waati in na, o waati la, nin waati in tun bɛ kɛ ko nin waati in tun bɛ kɛ ko nin waati in na, o waati la, nin ye ko ye min tɛ kɛ ni silikoni ye.
Kabini san 1965, ka fara seko minnu bɛ sen na, olu sabatili, u yiriwali, u yiriwali ani u baaracogo kan, mɔgɔw fana y’u ɲɛsin Organosilicon chimie baarabolo kura ma. Olu la, a kɔlɔsilenw ye: organosilicon stereochimie, organosilicon fɛnɲɛnamafagalan minnu bɛ ni farikolo baara ye, polisilan cyclique ani linear, silikoni suguya caman- farigan bɛ sɔrɔ cɛmancɛ la, silikon, ternaire ring fɛnɲɛnamafagalan minnu bɛ sɔrɔ silikon, silikɔn{3}metalne, coposilane, coposilane, olu sirili ni ɲɔgɔn cɛ. Sesquiloxanes, silicon-Polimɛri fɛnɲɛnamafagalan minnu bɛ dendɛrɛsi ni hyperbranched sɔrɔ, a ɲɔgɔnnaw Silikoni baara la, silikoni monomɛriw ni polimɛriw dilanni hakɛ bɛ ka bonya tuma bɛɛ, a dilanni fɛɛrɛ bɛ ka ɲɛtaa sɔrɔ tuma bɛɛ, wa a dilanni musakaw bɛ ka dɔgɔya tuma bɛɛ. O bɛ kɛ sababu ye ka silikoni fɛnw kɛ ɲɔgɔndan ye. Multi-Baarakɛcogo ni High{9}}Baarakɛminɛnw, i n’a fɔ furakɛli, fɛnɲɛnamafagalanw ani funteni-minɛn minnu bɛ se ka kɛ sababu ye ka u ka baarakɛcogo bonya, olu bɛ to ka taa ɲɛ. Silikɔni fɛnw bɛ don jamana sɔrɔko siratigɛ suguya caman na tuma bɛɛ a cogo kunbabaw la i n’a fɔ silikoni tulu, silikoni lastikuw, silikoni resin, ani silini kafolan.